Low hanging fruits
To avoid duplicate work on these, please leave a comment if you'd like to give some of these a shot.
Challenges
Regarding the c++ label for any PR that has file changes in src/:
For example, there might be a PR that makes changes to both lib/net.js and src/tcp_wrap.cc, but the overall net change in lib/net.js is substantially greater than that of src/tcp_wrap.cc. In that particular case I would normally just tag it with net only.
How to work on this
Its current labels brain is located in lib/node-labels.js#resolveLabels(). It's even covered by tests test/node-labels.test.js.
Refs nodejs/node#6247